| Title | Synthesis and characterization of highly conducting gel electrolytes |
|---|---|
| Publication Type | Articolo su Rivista peer-reviewed |
| Year of Publication | 1994 |
| Authors | Groce, F., Gerace F., Dautzemberg G., Passerini S., Appetecchi Giovanni Battista, and Scrosati B. |
| Journal | Electrochimica Acta |
| Volume | 39 |
| Pagination | 2187-2194 |
| ISSN | 00134686 |
| Keywords | Butyrlactone, Carbonates, Characterization, Electrochemical stability windows, Gel electrolytes, Gels, Immobilization, Ionic conduction, Lithium batteries, Lithium chlorate, Lithium compounds, Lithium hexafluoroarsenate, Lithium perfluorosulfonimide, Lithium transference number, Polyacrylonitriles, Polyelectrolytes, Solvents, Stability, Synthesis (chemical) |
| Abstract | The electrochemical properties of gel electrolytes formed by the immobilization in a poly(acrylonitrile) matrix of solutions of common lithium salts (eg LiClO4, LiAsF6 and LiN(CF3SO2)2) in organic solvents (eg the propylene carbonate-ethylene carbonate mixture, γ-butyrolactone or the γ-butyrolactone-ethylene carbonate mixture) have been determined. The results indicate that in accordance with previous literature data, these electrolytes have a high ionic conductivity, a wide electrochemical stability window and a high lithium transference number. However, their application in long-life, rechargeable lithium polymer batteries may be hindered by the instability of the negative electrode interface. © 1994. |
| Notes | cited By 234 |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0028516170&doi=10.1016%2f0013-4686%2894%29E0167-X&partnerID=40&md5=f8a6b36f9c77126792aa6d9fc8c22369 |
| DOI | 10.1016/0013-4686(94)E0167-X |
| Citation Key | Groce19942187 |
