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Sputtered WO3 films for water splitting applications

TitoloSputtered WO3 films for water splitting applications
Tipo di pubblicazioneArticolo su Rivista peer-reviewed
Anno di Pubblicazione2016
AutoriValerini, D., Hernández S., Di Benedetto Francesca, Russo N., Saracco G., and Rizzo A.
RivistaMaterials Science in Semiconductor Processing
Volume42
Paginazione150-154
ISSN13698001
Parole chiaveAmorphous films, Columnar structures, Crystal structure, Different thickness, Electrochemical characterizations, Energy gap, Oxide films, Oxides, Sputtering, Sputtering deposition, Tungsten, Tungsten compounds, Tungsten oxide, Tungsten oxide films, Water splitting, WO<sub>3</sub>
Abstract

Tungsten oxide films with different thickness were grown by sputtering deposition. Analysis of sample morphology showed that the films were constituted by sub-micrometric columnar structures, with diameters in the range 100-500 nm. As-deposited films revealed an almost-amorphous crystal structure and a wide optical band-gap of about 3.28 eV. Thermal annealing at 500 °C was used to promote the formation of a monoclinic WO3 crystal structure and the reduction of the band-gap. Photo-electrochemical characterizations were used to compare the responses of the different films and to evaluate their possible use in water splitting applications. © 2015 Elsevier Ltd.

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cited By 1

URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84958897635&doi=10.1016%2fj.mssp.2015.09.013&partnerID=40&md5=e7c4c095fe1213d8f80d4d3a36e1964a
DOI10.1016/j.mssp.2015.09.013
Citation KeyValerini2016150