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A novel ternary polymer electrolyte for LMP batteries based on thermal cross-linked poly(urethane acrylate) in presence of a lithium salt and an ionic liquid

TitoloA novel ternary polymer electrolyte for LMP batteries based on thermal cross-linked poly(urethane acrylate) in presence of a lithium salt and an ionic liquid
Tipo di pubblicazioneArticolo su Rivista peer-reviewed
Anno di Pubblicazione2008
AutoriRymarczyk, J., Carewska M., Appetecchi Giovanni Battista, Zane D., Alessandrini F., and Passerini S.
RivistaEuropean Polymer Journal
Volume44
Paginazione2153-2161
ISSN00143057
Parole chiaveAlkali metals, Cross linked poly(methyl methacrylate), Electrolysis, Electrolytes, Fluids, Ionic liquids, Ionization of liquids, Lithium, Lithium salts, LMP batteries, Polyelectrolytes, Polymer electrolytes, Polymers
Abstract

A new ternary polymer electrolyte based on thermally cross-linked poly(urethane acrylate) (PUA), lithium bis(trifluoromethansulfonyl)imide (LiTFSI) and the ionic liquid N-butyl-N-methylpyrrolidinium TFSI (PYR14TFSI) was developed and tested for application in LMP batteries. The polymer electrolyte was a transparent yellow self-standing material with quite good mechanical properties, i.e., comparable to that of a flexible rubber. The room temperature ionic conductivity of the dry polymer electrolyte was found to be as high as 0.1 mS cm-1 for the compound containing 40 wt% of ionic liquid (PYR14TFSI) and a O/Li ratio of 15/1 (Li+ from LiTFSI). The thermal analysis of the new cross-linked electrolyte showed that it was homogeneous, amorphous and stable over a wide temperature range extending from -40 °C to 100 °C. The homogeneity of the polymer electrolyte was also confirmed by SEM analysis. © 2008 Elsevier Ltd. All rights reserved.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-47249139910&doi=10.1016%2fj.eurpolymj.2008.04.026&partnerID=40&md5=2b666ce7dff9e4392cc2f65f44142472
DOI10.1016/j.eurpolymj.2008.04.026
Citation KeyRymarczyk20082153