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Annealing protocols for pyrrolidinium bis(trifluoromethylsulfonyl)imide type ionic liquids

TitoloAnnealing protocols for pyrrolidinium bis(trifluoromethylsulfonyl)imide type ionic liquids
Tipo di pubblicazioneArticolo su Rivista peer-reviewed
Anno di Pubblicazione2011
AutoriFurlani, M., Albinsson I., Mellander B.-E., Appetecchi Giovanni Battista, and Passerini S.
RivistaElectrochimica Acta
Volume57
Paginazione220-227
ISSN00134686
Parole chiaveAnnealing, Bis(trifluoromethane sulfonyl)imide, Chemical engineering, Crystal packings, DSC, Electrochemistry, Ionic liquids, Pyrrolidinium, Specific protocol, Thermal behaviors, Thermal history
Abstract

The phase transitions in ionic liquids (ILs) of the N-alkyl-N- methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR 1ATFSI) family show a common pattern, which implies a typical and characteristic crystal packing. Many of these features are also observed for the N-alkyl- Nmethylpiperidinium bis(trifluoromethanesulfonyl)imide (PIP 1ATFSI) family. Here we report the thermal behavior of some ILs of the PYR 1ATFSI and PIP 1ATFSI families and a few others having different anions. The thermal history was found to decide which phases will appear and, therefore, specific protocols were defined to obtain the desired phases in a reasonable amount of time. © 2011 Elsevier Ltd. All rights reserved.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-82955205884&doi=10.1016%2fj.electacta.2011.08.056&partnerID=40&md5=3cb5ecdbd3dcd8a73121f3dbdaccf4df
DOI10.1016/j.electacta.2011.08.056
Citation KeyFurlani2011220